Homogeneous catalysis mechanisms and industrial applications
"Providing a balanced treatment of the recent breakthroughs and developments while also detailing earlier discoveries and the fundamentals of homogeneous catalysis, the text provides problems and answers, along with real-life case studies, extensive references to cutting-edge research with appl...
| Otros Autores: | , |
|---|---|
| Formato: | Libro electrónico |
| Idioma: | Inglés |
| Publicado: |
Hoboken, New Jersey :
Wiley
[2014]
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| Edición: | Second edition |
| Colección: | Wiley ebooks.
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| Acceso en línea: | Conectar con la versión electrónica |
| Ver en Universidad de Navarra: | https://innopac.unav.es/record=b4612360x*spi |
Tabla de Contenidos:
- Title page; Copyright page; Preface; Chapter 1: Chemical Industry and Homogeneous Catalysis; 1.1 Feedstocks, Fuels, and Catalysts; 1.2 Crude Oil to Gasoline and Basic Building Blocks by Heterogeneous Catalysts; 1.3 Basic Building Blocks to Downstream Products by Homogeneous Catalysis; 1.4 Comparison among Different Types of Catalysis; 1.5 Catalyst Recovery; 1.6 Environmental Issues; Problems; Bibliography; Chapter 2: Basic Chemical Concepts; 2.1 Ligands; 2.2 Metals; 2.3 Important Reaction Types; Problems; Bibliography; Chapter 3: Methods of Investigation; 3.1 Catalytic Cycle and Intermediates.
- 3.2 Spectroscopic Studies3.3 Kinetic Studies; 3.4 Model Compounds; 3.5 Computational Methods; 3.6 Asymmetric Catalysis; Problems; Bibliography; Chapter 4: Carbonylation and Related Reactions; 4.1 Introduction; 4.2 Carbonylation and Manufacture of Acetic Acid; 4.3 Carbonylation of Other Alcohols; 4.4 Carbonylation of Methyl Acetate; 4.5 Carbonylation of Alkynes; 4.6 Other Carbonylation and Hydrocarboxylation Reactions; 4.7 C1 Chemistry; 4.8 Engineering Aspects; Problems; Bibliography; Chapter 5: Hydrogenation and Other Hydrogen-Based Catalytic Reactions; 5.1 Hydrogenation; 5.2 Hydroformylation.
- 5.3 Other Hydroformylation Reactions5.4 Asymmetric Hydroformylation; 5.5 Hydrosilylation; 5.6 Hydrocyanation; 5.7 Hydroamination; Problems; Bibliography; Chapter 6: Polymerization and Selective Oligomerization of Alkenes; 6.1 Introduction; 6.2 Early Catalysts for PE and PP; 6.3 Modern Ziegler-Natta Catalyst; 6.4 Mechanistic Studies; 6.5 Single-Site Catalysts; 6.6 Ethylene Polymerization with Polar Comonomers; 6.7 Polymers of Other Alkenes; 6.8 Oligomerization of Ethylene; 6.9 Engineering Aspects; Problems; Bibliography; Chapter 7: Selective C-C Bond-Forming Reactions with Alkenes.
- 7.1 Introduction7.2 Di-, Tri-, Tetramerization and Codimerization Reactions; 7.3 Metathesis Reactions; 7.4 Pd-Catalyzed Cross-Coupling Reactions; 7.5 Metal-Catalyzed Cyclopropanation and Cycloaddition; Problems; Bibliography; Chapter 8: Oxidation; 8.1 Introduction; 8.2 Wacker Oxidation; 8.3 Metal-Catalyzed Liquid-Phase Auto-oxidation; 8.4 Polymers from Auto-oxidation Products; 8.5 Selective Oxidations; 8.6 Engineering and Safety Considerations; Problems; Bibliography; Index; End User License Agreement.
