Phase transformations

Phase transformations

The book offers advanced students, in 7 volumes, successively characterization tools phases, the study of all types of phase, liquid, gas and solid, pure or multi-component, process engineering, chemical and electrochemical equilibria, the properties of surfaces and phases of small sizes. Macroscopi...

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Detalles Bibliográficos
Otros Autores: Soustelle, Michel, autor (autor)
Formato: Libro electrónico
Idioma:Inglés
Publicado: London : Hoboken, NJ : ISTE Ltd ; John Wiley & Sons 2015.
Colección:Wiley ebooks.
Chemical thermodynamics ; 5.
Acceso en línea:Conectar con la versión electrónica
Ver en Universidad de Navarra:https://innopac.unav.es/record=b40610810*spi
Tabla de Contenidos:
  • Table of Contents
  • Title
  • Copyright
  • Preface
  • Notations and Symbols
  • 1: Physico-Chemical Transformations and Equilibria
  • 1.1. Characteristic parameters of physico-chemical transformations
  • 1.2. Entropy production during the course of a transformation in a closed system
  • 1.3. Affinity of a transformation
  • 1.4. De Donder's inequality
  • direction of the transformations and equilibrium conditions
  • 1.5. Heats of transformation
  • 1.6. Set of points representing the equilibrium states of a transformation
  • 1.7. Closed systems accommodating multiple reactions
  • 1.8. Direction of evolution and equilibrium conditions in an open system
  • 1.9. Azeotropic transformations
  • 2: Properties of States of Physico-Chemical Equilibrium
  • 2.1. Laws of displacement of an equilibrium
  • 2.2. Properties of all the equilibria in a system
  • 2.3. Phase laws
  • 2.4. Indifferent states
  • 2.5. Thermodynamically-equivalent systems
  • 2.6. Stability of equilibria
  • 3: Molecular Chemical Equilibria
  • 3.1. Law of mass action
  • equilibrium constants
  • 3.2. Graphical representations of equilibria
  • pole diagrams
  • 3.3. Representation of the evolution of an equilibrium with the temperature
  • 3.4. Binary diagrams for chemical equilibrium
  • 3.5. Ternary diagrams of chemical equilibria
  • 3.6. Quaternary diagrams of chemical equilibria
  • 4: Determination of the Values Associated with Reactions
  • Equilibrium Calculations
  • 4.1. Reminders of a few thermodynamic relations
  • 4.2. Enthalpies of reaction
  • thermochemistry
  • 4.3. Reaction entropies
  • 4.4. Specific heat capacities
  • 4.5. Experimental determination of the equilibrium constants
  • 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data
  • 4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics.
  • 4.8. Thermodynamic tables and databanks
  • 4.9. Estimation of thermodynamic data
  • 4.10. Thermodynamic calculations for complex systems
  • APPENDICES
  • Appendix 1: Recap on the Reference States of Solutions
  • A1.1. Concentration and molar fraction
  • A1.2. Chemical potentials and activity coefficients
  • A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy
  • Appendix 2: Recap of statistical thermodynamics
  • A2.1. The three branches of statistics
  • A2.2. Partition functions of a molecule object
  • A2.3. Canonical partition function
  • A2.4. Canonical partition functions and thermodynamic functions
  • A2.5. Equilibrium constants and molecular partition functions
  • Bibliography
  • Index
  • End User License Agreement.

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